Ahh... I see what you mean. I thought you want to play a certain song when your computer starts, do you mean a startup sound?
If yes;
In Vista:Start >> Control Panel >> Hardware and Sound >> Under Sound, click Change system sounds >> Under
Program, click
Windows Logon.
Click
Browse to select a .wav file.
In XP: Start >> Control Panel >> Sounds and Audio Devices >> Sounds tab >> Under "Program Events", select Start Windows.
Again Click
Browse to select a .wav file.
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